작성일
2022.11.14
수정일
2023.06.28
작성자
강재욱
조회수
152

(172) B. Tyagi, N. Kumar, H.B. Lee, Y.M. Song, S. Cho, J. -S. Lee, J.-W. Kang* “Compact-Porous Hole-Transport-Layer for Highly Efficient Near-Infrared Region Transparent Perovskite Solar Cells for Tandem Applications” J. Alloys Compounds, 960, 170970 (2023) .

(172) B. Tyagi, N. Kumar, H.B. Lee, Y.M. Song, S. Cho, J. -S. Lee, J.-W. Kang* “Compact-Porous Hole-Transport-Layer for Highly Efficient Near-Infrared Region Transparent Perovskite Solar Cells for Tandem Applications” J. Alloys Compounds, 960,  170970 (2023) . 첨부 이미지

Highlights


  • The cp-NiOx films were consecutively fabricated using spin-coating and spray-coating techniques.

  • The cp-NiOx/perovskite interface possesses lower buried defects.

  • The cp-NiOx films have mesoporous surface morphology and excellent surface properties for perovskite film formation.

  • Wide-bandgap perovskite solar cell consisting cp-NiOx HTL yielded PCE of ∼15.95 % and NIR transmittance (>92 %).

  • 4T perovskite/silicon tandem cells based on the cp-NiOx HTL yielded a PCE of 26.0 % with superior stability.


Abstract

Wide-bandgap perovskites solar cells (PSCs) are vital as top cells in perovskite-based tandem solar cells (TSCs). However, poor band alignment with the charge transport layer and unwanted parasitic absorption in the top semitransparent-PSC (ST-PSC) are major factors limiting the power conversion efficiency (PCE) of TSCs. Herein, we present a compact-porous nickel oxide (cp-NiOx) hole-transport layer (HTL) sequentially fabricated using a sol-gel suspension and colloidal suspension of highly crystalline NiOx. The cp-NiOx film exhibited enhanced transparency, mesoporous surface morphology, and better energy band alignment with a 1.68 eV perovskite film for fabricating highly near-infrared transparent (∼92 % (@800–1200 nm)) ST-PSCs. The best cell achieved a PCE of 15.9 %. In addition, a four-terminal perovskite/silicon TSC based on the cp-NiOx HTL achieved an outstanding PCE of ∼26.0 %. The tailored energy band structure and reduced parasitic absorption in the near-infrared region of the ST-PSCs based on the cp-NiOx HTL enabled fabrication of highly efficient inverted ST-PSCs for perovskite/silicon TSCs.

https://www.sciencedirect.com/science/article/pii/S0925838823022739

- Submission (2022. 9. 20)

- Revision (2023. 5. 10)

- Published (2023.10. 15)

첨부파일
첨부파일이(가) 없습니다.
다음글
(173) N. Kumar, H.B. Lee, B. Tyagi, M.M. Ovhal, S. Cho, J.-S. Lee, J.-W. Oh, J.-W. Kang* “Spray deposited, virus-templated SnO2 mesoporous electron transport layer boosting the performance of perovskite solar cells” Solar RRL, 7, 2300065 (2023)
강재욱 2022-11-14 22:03:31.0
이전글
(171) M.M. Ovhal, H.B. Lee, S. Boud, K.-J. Ko, W.-Y. Jin, N. Kumar, B. Tyagi, J.-W. Kang* “Flexible, stripe-patterned organic solar cells and modules based on multilayer-printed Ag fibers for smart textile applications” Materials Today Energy, 34, 101289 (2023)
강재욱 2022-11-14 21:55:41.0